Modeling Radioactive Decay: Solving an IVP for a Series of Three Elements

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SUMMARY

The discussion focuses on modeling radioactive decay through a system of differential equations for three elements: X, Y, and Z, where Z is stable. The initial conditions specify that there are 100e moles of element X at time zero, and after two hours, both X and Y stabilize at 100 moles each. The equations governing the decay process include dw/dt = -kW, dx/dt = kW - cX, dy/dt = cX - aY, and dz/dt = aY, with k, c, and a as distinct constants. A critical correction was made regarding the sign of the first equation to ensure conservation of mass across the elements.

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  • Understanding of differential equations and initial value problems (IVP)
  • Familiarity with radioactive decay processes and kinetics
  • Knowledge of mathematical modeling techniques
  • Proficiency in using constants in equations for decay rates
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  • Learn about conservation laws in chemical kinetics
  • Explore the application of systems of differential equations in modeling decay processes
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nate9519
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1. The Problem

Construct a mathematical model (system of differential equations) for a radioactive series of 3 elements. X,Y, and Z (Z is a stable element). (Note: W decays into X, X decays into Y, and Y decays into Z). At time zero there are 100e (approx. 271.828) moles of element X. After two hours there are exactly 100 moles each of elements X and Y. Solve the IVP and calculate the number of moles for each of the three elements after i) 1 hour and ii) 5 hours

2. Homework Equations

dw/dt = kW
dx/dt = kW - cX
dy/dt = cX - aY
dz/dt = aY
( k ,c ,and a are all different constants)
x(0) = 100e
x(2) = 100
y(2) = 100 3. Attempt at solution

Im posting this to see if i have my system set up correctly. I am not looking for an answer.
 
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nate9519 said:
1. The Problem

Construct a mathematical model (system of differential equations) for a radioactive series of 3 elements. X,Y, and Z (Z is a stable element). (Note: W decays into X, X decays into Y, and Y decays into Z). At time zero there are 100e (approx. 271.828) moles of element X. After two hours there are exactly 100 moles each of elements X and Y. Solve the IVP and calculate the number of moles for each of the three elements after i) 1 hour and ii) 5 hours

2. Homework Equations

dw/dt = kW
dx/dt = kW - cX
dy/dt = cX - aY
dz/dt = aY
( k ,c ,and a are all different constants)
x(0) = 100e
x(2) = 100
y(2) = 100


3. Attempt at solution

Im posting this to see if i have my system set up correctly. I am not looking for an answer.

Looks good to me, except for the first equation: dw/dt = -kw, which I suspect is a typo. [Note adding up all of the rates gives you conservation of atoms, d[W+X+Y+Z]/dt = 0, and you won't get this unless the first equation is -kw.]
 
Quantum Defect said:
Looks good to me, except for the first equation: dw/dt = -kw, which I suspect is a typo. [Note adding up all of the rates gives you conservation of atoms, d[W+X+Y+Z]/dt = 0, and you won't get this unless the first equation is -kw.]
would kW in dx/dt need to be negative also? and would dz/dt need to be negative?
 
No and no. kW is the rate of formation of x from W. dz/dt is the rate of accumulation of z, in this case simply from Y without any further decay.

You really should decide what symbol you are going to use for w, x, y, z, CAPS or lower case. - could that have helped confuse you?
 

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