They didn't know what that number was when they invented that concept of mole. You can understand moles without knowing this number. It was just the number of atoms in a gram of hydrogen, even when we didn't knlwnwhat that number is. It still is! - almost. (Best to ignore the refinements if you're having such difficulties.) Different atoms combine with each other to form compounds with (in the beginning) small whole numbers of atoms of different elements, e.g. water has one atom of oxygen and two of hydrogen, methane has one of carbon and four of hydrogen. But the atoms of hydrogen, oxygen and carbon all have different masses, that of oxygen is about.16 times that of hydrogen, of carbon about 12 times that of hydrogen. So water combines two grams of hydrogen to one of oxygen so by grams they combine about 2:16 = 1:8. In grams, methane is about 4:12 = 1:3 in grams. The same numbers carry over to other compounds so the combination to make carbons dioxide (one atom carbon and two oxygen) is 12:2×16 = 1:1.66 . The combining numbers are easy to immagine - but they are not easily visibile in the laboratory - what you could measure in laboratories was combining weights. Still true for what people mostly do in chemistry. Hence all this science of stoichiometry, and all the calculations about it in excercises.
Which many students seem to have enormous difficulty with. Yet they involve nothing but simple proportions. So I wonder why the difficulty? I guess it is because one science is called chemistry and the other is arithmetic. And when they do one they can't carry the other over and mix them.
Another related problem is perhaps the rather algebraic-like notation for chemical compounds. Maybe if they wrote coloured blobs for atoms, say a white one for hydrogen a black on for oxygen and remembered the White on weighs 1 and the black one 16 they would get it.
However I think what I said in the first para is in your textbook so I hope re-reading it you can undesrstand it there, and bear in mind you can't expect us to write the textbooks again.