When jump-starting a car, it's recommended to connect the positive terminals first and then the negative to a grounded metal surface away from the battery to prevent sparks that could ignite hydrogen gas. While some users report connecting negative terminals directly without issues, the safety practice stems from concerns about hydrogen gas emissions during charging. Older vehicles sometimes had positive chassis, influencing traditional jump-starting methods. The discussion highlights the importance of ensuring a secure connection and understanding the risks associated with battery gases. Overall, following the established safety protocols is advised to avoid potential hazards.