When a positive charge and a negative charge are attracted to each other, their potential energy decreases as they move closer, converting energy into kinetic energy. If discussing voltage, the system behaves like a capacitor, where the voltage decreases as the charges come closer due to a reduction in capacitance. Conversely, if the charges start close together, work must be done to separate them, resulting in an increase in potential difference. The relationship between charge, voltage, and capacitance is crucial in understanding these dynamics. Overall, the potential changes based on the relative positions and movements of the charges involved.