Plastics to tolerate -300F for liquid nitrogen generation

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Discussion Overview

The discussion revolves around the challenges of selecting appropriate tubing materials for transporting very cold gases at -300°F, specifically in the context of generating liquid nitrogen from air. Participants explore various plastic and metal options suitable for cryogenic applications.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant inquires about plastic tubing materials that can withstand -300°F, noting that polycarbonate is insufficient.
  • Another participant suggests that teflon tubing might be a viable option for this application.
  • A different viewpoint expresses skepticism about the suitability of plastics at such low temperatures, arguing that they tend to become brittle and that metals may be more appropriate due to their better temperature range.
  • A participant mentions that cryogenic delivery hoses are typically multilayer metal devices and references a specific product link.
  • One participant shares that polypropylene storage vials might not be suitable for cryogenic tubing, indicating concerns about material performance at low temperatures.
  • Another participant advises that while teflon could work, it should be secured to prevent vibration, which could lead to breakage, and warns against bending the tube once cold.
  • This participant also emphasizes the risks associated with plastic tubes at cryogenic temperatures, sharing personal experience of a tube bursting and the potential hazards involved.

Areas of Agreement / Disagreement

Participants express differing opinions on the suitability of plastic versus metal tubing for cryogenic applications, with no consensus reached on the best material. There are multiple competing views regarding the performance of specific plastics at low temperatures.

Contextual Notes

Participants highlight the limitations of certain materials at cryogenic temperatures and the potential for sudden failures in plastic tubing, but do not resolve the specific material choices or performance characteristics.

imsmooth
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Maybe someone here will have an idea where I can get some information. I am planning on making liquid nitrogen from air and will need to regenerate waste gas. This gas will be very cold (-300F) and will get transported through some tubing system. Is anyone aware of any plastic tubing material that will tolerate these temperatures? Polycarbonate is the best I have found so far, but it is not good enough.

Otherwise, I will have to use metal tubing.
 
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I'm thinking teflon tubing might work. Any thoughts?
 
If you need some plasticity, anything that won't turn brittle at these temperatures will be either liquid or extremely soft at room temperatures. Any basic materials you can find to work with will be extremely brittle at -300°F. I would bet on metals being more suitable than plastics, as they tend to have a better range of temperatures. There are some alloys that are designed for low temperatures that aren't prohibitively soft at room temperatures to be worked with.
 
imsmooth said:
Maybe someone here will have an idea where I can get some information. I am planning on making liquid nitrogen from air and will need to regenerate waste gas. This gas will be very cold (-300F) and will get transported through some tubing system. Is anyone aware of any plastic tubing material that will tolerate these temperatures? Polycarbonate is the best I have found so far, but it is not good enough.

Otherwise, I will have to use metal tubing.

Cryogenic delivery hoses are typically multilayer metal devices:

http://www.sigmasystems.com/accessories-tp/hoses/cryo-hoses.htm

The storage vials I use are made of polypropylene, but I think that material would be a poor choice for cryogenic tubing.
 
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Teflon should be ok. Just make sure you attach it to something so that it can't vibrate (which it will do if you pump LN2 through it) since this will cause it to eventually break. You will NOT be able to bend the tube once it is cold without breaking it, but I hope you've already realized that (If you want a bendable tube you need something metallic).
Also, use an armoured tube if you can find it. It will reduce the chance of the tube exploding. Note my choice of words, when an plastic tube at 77K bursts it does so in quite an spectacular fashion resulting it lots of small bits of plastic (I am speaking from experience here).
Note also that a tube can work really well for years and then suddenly fail, I would not recommend being too close to an uprotected tube (I've had a LN2 shower once when a tube burst, I don't recommend it).
 

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