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## Main Question or Discussion Point

Hey there - I

The above images are Mathematica's plots of |ψ(2, 1, -1)|², |ψ(2, 1, 0)|², |ψ(2, 1, 1)|², respectively. As you can see, the first and third are identical, and not the shape of 2p orbitals, while the second plot actually looks like what I would expect - one of the three 2p orbitals.

Here is my wave function - it's possible that the conversion from spherical to Cartesian coordinates is a problem, but I'm not sure:

If the above needs clarifying, do ask. Thanks for any help in advance ;)

*think*I have an issue with my 3D density plots of the probability density of the Coulomb wave function. The reason I think something is going wrong is because my plots of |ψ(n=2, l=1, m=-1)|² and |ψ(2, 1, 1)|² are identical, while I would expect them to have the same shape but be rotationally symmetric along different orthogonal axes.The above images are Mathematica's plots of |ψ(2, 1, -1)|², |ψ(2, 1, 0)|², |ψ(2, 1, 1)|², respectively. As you can see, the first and third are identical, and not the shape of 2p orbitals, while the second plot actually looks like what I would expect - one of the three 2p orbitals.

Here is my wave function - it's possible that the conversion from spherical to Cartesian coordinates is a problem, but I'm not sure:

If the above needs clarifying, do ask. Thanks for any help in advance ;)