Yes that Wikipedia link was not a good choice.
I think this subject suffers from unclear teaching, same as "why does a rocket go".
The reason there's no external voltage is there's equal and opposing potentials inside and outside the depletion region.
Were this not so, a diode would deflect a voltmeter.
Here's a more scholarly writeup
http://ecee.colorado.edu/~bart/book/book/contents.htm
this section goes to to your question:
http://ecee.colorado.edu/~bart/book/book/chapter4/ch4_3.htm
and page 21 of this link gives a picture that paints for me the mental image i need to work it in my head:
http://www.scribd.com/doc/6661380/The-Junction-Diode2
look at the picture on p21 entitled "Diodes - The Depletion Region"
let us do a thought experiment on that picture.
1. Connect a wire from the left side of p region to right side of n region, so that the n and p regions are at same potential.
No current can flow through that wire because the depletion region prevents current flow between n amd p regions.
2. Imagine yourself very small, small enough to walk among the atoms in the silicon crystal.
Imagine also you are carrying a unit positive charge in one hand.
Imagine also you are equipped with a meter that can integrate the product of Force acting on your Unit Charge X Distance traversed. This would be the work done in moving the charge.
Recall what is potential - potential is work done in moving a unit charge from one place to another.
Absolute potential is work to move a charge from infinity to where you are, which is impractical because you can't get out there to make the measurement.
So we always pick some place for a reference and measure potential with respect to that point, hence voltage is a potential "Difference".
So let's call your [edit ]
force X distance meter [ /edit] a "Potential Meter". And let's say potential increases when we have to supply the work.
3. Imagine yourself inside the silicon at the left side of p region where wire connects.
You see the crystal structure, orderly atoms with an occasional missing electron.
You set your "potential meter" to zero here.
4. Walk toward right approaching depletion region, and watch your potential meter.
We are approaching a region that has excess electrons, which attract our positive charge, so we are extracting work not supplying it.
Potential meter is decrementing because we are being pulled not pushed.
Note reading when you reach the p edge of depletion region. Negative.
5. Enter depletion region, continue to right. Now we are moving away from negative charge toward positive, so force on our our unit positive charge is other direction, pushing against our travel. Instead of extracting work we are having to supply it. Potential meter is now incrementing.
6. Continue moving right. Note meter reading when you reach n edge of depletion region.
Positive.
7 . Continue moving right through n region. We are moving away from a region of positive charge so force is once again in direction of our travel. Meter resumes incrementing. Note meter reading at right edge of N material.
I submit that your potential meter MUST read zero at three places:
far left where we started,
middle of depletion region,
far right where we ended.
and i submit readings at edges of depletion region are equal and opposite.
My model does not agree with the idealization Maverick pointed out in bold above, 'no field outside depletion region'.
That's doubtless so at distances greater than depletion region's width where distances to positive and negative regions are about the same.
What really goes on at the outside edge of depletion region?
If there's no gradient there, it seems to me it violates Kirchoff.
But i could be wrong.
Different explanations click for different people.
Here's another related PF thread
https://www.physicsforums.com/showthread.php?p=2658119#post2658119
old jim