But your identity is in Wiki:
[PLAIN]http://upload.wikimedia.org/math/3/a/b/3ab61b65f059221cc748b304a6a5c7a8.png[/QUOTE]
So continuing the discussion after 30 months :-)
Thank you for outlining the proof, drpepper0708.
Since my question below involves the detailes of conventions, etc, let me summarize all the ingredients of the proof.
If one starts from the identity
\begin{equation}
i\epsilon^{\sigma\mu\nu\rho}\gamma_\sigma \gamma_5 = \gamma^{\mu\nu\rho} ,\;\;\;\;\;\;\;\;\;(\ast)
\end{equation}
expanding the right hand side and using only the Clifford algebra,
\begin{equation}
\{\gamma_\mu ,\gamma_\nu \} = 2g_{\mu\nu},
\end{equation}
one finds the identity
\begin{equation}
\gamma^\mu\gamma^\nu \gamma^\rho = g^{\mu\nu}\gamma^\rho + g^{\nu\rho}\gamma^\mu-g^{\mu\rho}\gamma^\nu + i\epsilon^{\sigma \mu\nu\rho}\gamma_\sigma \gamma_5 .\;\;\;\;\;\;\;\;(\ast \ast)
\end{equation}
Now, the identity (*) can be proven be expanding the left hand side using
\begin{equation}
\gamma_5 = \frac i{4!}\epsilon_{\mu\nu\rho\sigma}\gamma^\mu\gamma^\nu \gamma^\rho \gamma^\sigma ,
\end{equation}
and then using the Clifford algebra as well as
\begin{equation}
\{\gamma_5 , \gamma_\mu\} =0
\end{equation}
and
\begin{equation}
\epsilon^{\alpha\mu\nu\rho}\epsilon_{\alpha\sigma\lambda\kappa} = -3! \delta^{[\mu}_{\sigma}\delta^\nu_\lambda\delta^{\rho]}_\kappa .
\end{equation}
The last equation is valid on four-dimensional manifolds with Lorentzian signature. It can be found in more generality in e.g. Carroll.
Using only these ingredients, I find that the proof goes through.
Now to the question!
As noted by arkajad, the identity (**) is also on wikipedia
http://en.wikipedia.org/wiki/Gamma_matrices,
but the last term differs by a sign.
I can't seem to figure out how this sign comes in. I assume it is a matter of conventions. However, both wikipedia and the proof by drpepper0708 use the same conventions,
\begin{equation}
\{\gamma_\mu ,\gamma_\nu \} = 2g_{\mu\nu},
\end{equation}
and
\begin{equation}
\gamma_5 = \frac i{4!}\epsilon_{\mu\nu\rho\sigma}\gamma^\mu\gamma^\nu \gamma^\rho \gamma^\sigma .
\end{equation}
Am I missing an obvious mistake?
I very much invite anyone to redo these computations and find a possible reason for the differing sign.
Cheers!