PV Diagram of a monoatomic gas and diatomic gas

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SUMMARY

The discussion focuses on the PV diagram of monoatomic and diatomic ideal gases during isothermal compression and adiabatic expansion. The key difference lies in the internal energy changes due to the distinct heat capacities of monoatomic and diatomic gases, which affect their final internal energies. The adiabatic condition, expressed as PVγ = K, is crucial for analyzing the expansion paths of both gas types. Understanding these differences is essential for accurately sketching the PV diagrams for each gas type.

PREREQUISITES
  • Understanding of ideal gas laws and PV diagrams
  • Knowledge of isothermal and adiabatic processes
  • Familiarity with heat capacities of monoatomic and diatomic gases
  • Concept of internal energy and its relation to temperature and degrees of freedom
NEXT STEPS
  • Study the derivation and implications of the adiabatic condition PVγ = K
  • Explore the differences in heat capacities for monoatomic and diatomic gases
  • Learn how to calculate internal energy changes during isothermal and adiabatic processes
  • Investigate graphical representations of PV diagrams for various gas types
USEFUL FOR

Students and educators in thermodynamics, physicists, and engineers interested in gas behavior and thermodynamic processes.

Zenderson3
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I'm reviewing a question on a previous test but am having trouble finding the solution for it.

We were told to draw a PV diagram of a monoatomic ideal gas that undergoes an isothermal compression from Va to Vb and then is allowed to expand adiabatically and quasistatically back to Va again.

I was able to comprehend this portion of the question fine but then got stuck on the next part that asked how this sketch would look if the molecule was diatomic. Aside from the difference in internal energy due to the degrees of freedom of a diatomic molecule I can't seem to find any other major implications of a monoatomic gas vs. a diatomic gas. Furthermore I can't seem to figure out how the internal energy of the system would tie into this diagram.
 
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Zenderson3 said:
I'm reviewing a question on a previous test but am having trouble finding the solution for it.

We were told to draw a PV diagram of a monoatomic ideal gas that undergoes an isothermal compression from Va to Vb and then is allowed to expand adiabatically and quasistatically back to Va again.

I was able to comprehend this portion of the question fine but then got stuck on the next part that asked how this sketch would look if the molecule was diatomic. Aside from the difference in internal energy due to the degrees of freedom of a diatomic molecule I can't seem to find any other major implications of a monoatomic gas vs. a diatomic gas. Furthermore I can't seem to figure out how the internal energy of the system would tie into this diagram.
The same work is done on or by the gases during the compression and expansion parts. But their heat capacities are different. So their changes in internal energies in the isothermal compression part will be different which means that their final internal energies will differ.

The adiabatic condition: PV^\gamma = K applies during the adiabatic expansion. Use this to determine how the adiabatic expansion path for the diatomic gas will compare to that of the monatomic gas.

AM
 

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