Raman Shifts of Metals for PhD Students

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nicolas khoury
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hello,
I'm a Phd student my Phd subject is about surface enhanced spectroscopy (SERS). i need a reference for the Raman Shifts of metals (ex: Gold (colloid or film), titan tungesten..). Plz if anyone can help me.
thank you in advance
Nicolas
 
It is black silicon (microstructured surface) on which were formed of gold clusters arranged substantially periodically follows a gold sputtering, and to attached the gold clusters they used titan tungsten TiW. I have a my own spectre of these three materials, but i need to confirm my results. I have a reference for the Black-Si but i need a reference for the other materials.
 
Hi. I have got question as in title. How can idea of instantaneous dipole moment for atoms like, for example hydrogen be consistent with idea of orbitals? At my level of knowledge London dispersion forces are derived taking into account Bohr model of atom. But we know today that this model is not correct. If it would be correct I understand that at each time electron is at some point at radius at some angle and there is dipole moment at this time from nucleus to electron at orbit. But how...

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