Hi James
Alpha Centauri is composed of three separate stars, A, B & Proxima. The Milky Way, our Galaxy, contains our Sun, the Alpha Centauri system and over 100 billion other stars in a vast system of stars that's over 100,000 light years wide. Alpha Centauri's stars are a mere 4.2-4.4 light years away (depending on which component we're talking about) and can be reached within a human lifetime without the need to go faster than light.
Perhaps you meant 1/25 of the speed of light? In that case the trip takes 105-110 years, which is a bit longer than an average human lifespan of 70-80 years.
A point your other responders neglect to mention is the need to accelerate to high speed in order to make relativistic effects usefully noticeable. For example at an acceleration of just 1 gee (equivalent to Earth's surface gravity) the trip to Alpha Centauri A or B takes 6.035 years from the point of view of people staying on Earth. On board ship the journey takes just 3.58 years. Increasing the acceleration decreases the trip-time perceived by the crew quite significantly. If the crew can be protected against a full 25 gee, then the trip takes ~0.368 years (19 weeks.) From the viewpoint of the people at home it's ~4.437 years.
An accelerometer measures, obviously enough, the acceleration, moment to moment. An integrating accelerometer produces a 'speed' (called the rapidity in relativistic terminology) that is the acceleration multiplied by the time spent accelerating, adding up all those small moments over the whole trip. According to the ship-board integrating accelerometer the top speed measured is 1.85 times lightspeed for the 1 gee trip to Alpha Centauri and 4.6 times lightspeed for the 25 gee trip. To accelerate to x25 lightspeed, according to the integrating accelerometer of the ship, the time required is 24.2 years ship-time at 1 gee and the ship travels ~16 billion light years doing so. At 25 gees that trip takes 0.97 years and the ship travels 1.4 billion light years. From a stationary observer the ship never exceeds the speed of light.
That's relativity for you!