Reading a Binary Phase Diagram (lever rule etc.)

Click For Summary
The discussion revolves around analyzing a phase diagram for a mixture of 20WT% A and 80WT% B cooling from liquid. The first solid appears at approximately 820°C, identified as the β phase with a composition of about 94%B and 6%A. Just below the eutectic temperature, the phases present are α and β, with compositions of 91%B and 9%A. Weight fractions of these phases are calculated using the lever rule, with the β phase comprising 22.9%B and 77.1%A, while the α phase consists of 78%A and 22%B. Clarifications are made regarding the correct pivot point for the lever rule calculations, emphasizing the overall composition of the mixture.
cookiemnstr510510
Messages
162
Reaction score
14
Hello All,
Wanted to see if I am approaching this problem correctly, I have an exam coming up and am pretty sure something like this will show up.

Examine the phase diagram (phase.jpg) with a 20WT% A and 80WT%B which is allowed to cool slowly from liquid

A) what temp does the first solid appear?
B)What phase it is?
C)what is its composition?
D)What phases are present just below the eutectic temperature?
E) What are the compositions of these phases?
F) What are the weight fractions of these phases?

My attempt:

A) From the graph I would say about 820°C
B) The first solid is β phase (since the only things are L+β)
C)The composition is about 94%B and 6%A
D) The phases present just below the eutectic are α+β
E) 91%B and 9%A
F) This is where you have to use the lever rule:
For β phase:
wt%=##\frac{91-72}{91-9}##*100%=22.9%B
The composition of β: 22.9B and 77.1A

For α phase:
wt%=##\frac{72-8}{91-9}##*100%=78%A
The composition of α: 78%A and 22%B

Thanks in advanced!
 

Attachments

  • Phase.png
    Phase.png
    34.5 KB · Views: 624
Engineering news on Phys.org
A) To my eye, nearer 840 or 850, but just an estimate.
B) - D) OK
E) Question asks for composition of both phases.
F) The axis about which the lever pivots is not the eutectic composition, but the overall composition of the mixture. (Test your answer: if you have x% α with composition 8% B, and y% β with composition 91% B, do you have 80% B overall?)
 
  • Like
Likes cookiemnstr510510
I need to anneal 5052 aluminum for a home project. Google has given me mixed results on how to do this. Short version is that I'm doing some heavy forming on a piece of 5052-H32 and I'm running into issues with it work hardening. I've tried the Sharpie trick with a propane torch. But I'm not sure this is doing anything. I'm also seeing conflicting opinions whether to quench or air cool. So I'm looking for some expert opinions. (Oven heating is not an option due to size.) Thanks. edit: The...

Similar threads

  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 33 ·
2
Replies
33
Views
3K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 3 ·
Replies
3
Views
7K
  • · Replies 2 ·
Replies
2
Views
3K
Replies
1
Views
2K
Replies
1
Views
9K
  • · Replies 7 ·
Replies
7
Views
82K
Replies
4
Views
3K