Recursion relation in the hydrogen atom

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SUMMARY

The discussion centers on the recursion relation for calculating eigenstates of the hydrogen atom, specifically the formula b_{j} = 2 \frac{kj - a}{j(j+1)-l(l+1)} \cdot b_{j-1}. Participants explore the implications of b_{j-1} = 0, questioning how b_{j=l} can be non-zero despite the preceding term being zero. The conversation highlights the indeterminate form 0/0 that arises and suggests using L'Hôpital's rule to analyze the limit as j approaches l. Additionally, the discussion contrasts this formula with a more commonly referenced one, c_{j+1}=\frac{2(j+l+1-n)}{(j+1)(j+2(l+1))}c_{j}.

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  • Understanding of recursion relations in mathematical physics
  • Familiarity with eigenstates and quantum mechanics
  • Knowledge of limits and L'Hôpital's rule
  • Basic concepts of the hydrogen atom's quantum numbers
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  • Research the derivation of eigenstates in quantum mechanics
  • Study the application of L'Hôpital's rule in indeterminate forms
  • Explore alternative recursion formulas for quantum systems
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Students and researchers in quantum mechanics, particularly those studying the hydrogen atom and recursion relations in mathematical physics.

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Homework Statement


Given the following recursion formula:

b_{j} = 2 \frac{kj - a}{j(j+1)-l(l+1)} \cdot b_{j-1}

(where a, k and l are constants) how can

b_{j = l} \neq 0 if b_{j - 1} = 0.

Homework Equations



The Attempt at a Solution



This is a part question and I really can't see why. if bl-1 = 0 then bl = 0 also. But then all subsequent bj as well !
 
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Well firstly bj=l = (2(kl-a))/0*bj-1 thus if bj-1 = 0 we come to the indeterminant form 0/0 . This implies that bj=l could possibly be nonzero. I know this isn't very mathematically rigorous, but I suppose you could try l'hopital's rule on the first equation with respect to l.
 
grindfreak said:
you could try l'hopital's rule on the first equation with respect to l.

hi, I don't see how that would help. surely you'd have to differentiate w.r.t. j and take the limit as j → l but my understanding is that the bj are constants not dependent on j so the factor bj-1=0 would remain after differentiating.
 
Perhaps not l'hospital's rule, but the only way that bl-1 can equal zero is if kl-a=0 or l=a/k. This also makes the numerator of bl=j = 0 as well as it's denominator. Since you end up with the indeterminate form of 0/0, we don't know for sure that bl=j = 0 and thus might actually be nonzero. I believe your problem was looking for speculation and not necessarily a formal proof.
 
second question, how would you use this recursion formula? If bj-1:= 0, then when moving forward with increasing j all subsequent bj would also equal zero. Is it possible to move back from a non zero upper limit perhaps j = n, where n is the main quantum number.
 
Hmmm, I'm not sure about moving backwards since, like you've stated, every bj is zero due to the fact that every numerator of the recursion is zero. The one exception being bj=l where both the denominator and the numerator are zero. Since this is the case, we end up with an indeterminate form. Now where to go from there I'm not sure, since it is neither zero, nor infinite, there is definitely a chance that it is nonzero. But, judging by how the question is worded I don't think they're looking for a rigorous proof, but how it is possible that it is nonzero.
 
hi, this formula is used to calculate the eigenstates of the hydrogen atom (at least that's the context of how we derived it in class) so it should produce a range of non-zero results. It's weird because I can't find this formula in the literature, all the books I know use a different one without the pole at j = l
 
Yes I noticed this, most texts use:

c_{j+1}=\frac{2(j+l+1-n}{(j+1)(j+2(l+1))}c_{j}\

I believe.
 

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