Polarization in waveguides is a complex topic, particularly regarding the propagation of TEM waves, which cannot travel in waveguides due to their requirement for both electric and magnetic fields to be perpendicular to the direction of propagation. Instead, waveguides support TE (Transverse Electric) and TM (Transverse Magnetic) modes, where either the electric or magnetic field has a longitudinal component. The fundamental mode in rectangular waveguides is TE10, where the electric field is perpendicular to the direction of propagation. The discussion highlights that while the electric field orientation can be horizontal or vertical, it is crucial to understand the field configurations and their interactions with the waveguide's geometry. Overall, the conversation emphasizes the need for clarity on how these fields behave within waveguides and their implications for polarization.