Understanding Hydrogen Selection Rules: Emission vs. Absorption and the p-Series

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SUMMARY

The discussion centers on the hydrogen selection rules, specifically the differences between emission and absorption processes in the context of the p-series. It is established that selection rules permit transitions with Δl=±1, which applies to both emission and absorption, although the figure presented primarily illustrates emission. The p-series is defined as the only series observed in absorption transitioning to the ground state. The conversation clarifies that while absorption is theoretically possible, practical observation is limited due to the rarity of the necessary conditions.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly selection rules.
  • Familiarity with atomic transitions and energy levels in hydrogen.
  • Knowledge of emission and absorption spectra.
  • Basic grasp of the p-series in atomic physics.
NEXT STEPS
  • Study the implications of Δl=±1 in quantum transitions.
  • Research the characteristics of the hydrogen emission spectrum.
  • Explore the conditions necessary for observing absorption lines in hydrogen.
  • Learn about the significance of the p-series in spectroscopy.
USEFUL FOR

Students of physics, particularly those focusing on quantum mechanics and atomic spectroscopy, as well as educators and researchers interested in the behavior of hydrogen transitions.

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Please see attachment. What are the arrow heads supposed to mean? Only emission is allowed and no absorption?
I mean, selection rules allow Δl=±1. But the figure is saying otherwise.

I also read in another book, that the only series observed in absorption is that to the ground state, where it is called the p-series.

Please explain, I am kind of lost in figures and resources.
 

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The image is drawn for emission only - absorption is possible, too, if you have some source of light. The combination of excited atoms plus light of the right frequency for a transition can be rare, however.
 
But if I reversed the arrows in this figure so that I aim to draw a figure of absorption, all drawn lines will be possible, no?
(i.e, if I reversed the heads with tails of all arrows presented in the figure).
 
They are possible, but you won't see most absorption lines if you shine light on hydrogen in its ground state.
 
Ok, thanks, I just wanted to make sure of they were possible! As selection rules explain. Thanks again.
 

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