Solving a Heat Transfer Problem with an Insulated Vessel and Fan-Induced Rupture

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The discussion revolves around solving a heat transfer problem involving an insulated vessel with two compartments, one empty and one containing air. The key points include determining the temperature at which the membrane ruptures and calculating the work done by the fan. For part (c), it is clarified that the air does not perform work during expansion since the additional compartment is empty, leading to no energy loss and maintaining constant temperature. This conclusion challenges common assumptions about gas behavior during expansion, as the temperature remains unchanged despite the expansion. Ultimately, the analysis confirms that the initial and final temperatures of the air are equal due to the isolated nature of the system.
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I've been working on the following problem for several hours but am not sure how to approach part (c).

Consider the insulated vessel shown here, with compartment A of volume 0.03 m3, which is empty, and separated by an insulating membrane from compartment B of volume 0.01 m3, which contains 0.15 kg of air at 25°C. The air is stirred by a fan until the membrane ruptures. The membrane is designed to rupture at a pressure of 2 MPa.

http://img375.imageshack.us/img375/6605/37jf9.jpg

a) What is the temperature when the membrane ruptures?
b) Calculate the work done by the fan.
c) Find the pressure and temperature of the air after the membrane ruptures and the air reaches equilibrium state.


For part (c), I'm not sure which equation to apply. I'm attempting to get the temperature T first and then insert that into the gas law equation to find the pressure. Neglecting kinetic, potential and other energies, the law of conversation of energy would say that

(mc \Delta_T)_{before rupture} = (mc \Delta_T)_{after rupture}.

Am I on the right track? If so, I'm confused about which values of Tfinal and Tinitial to apply to delta T on both sides. Please help me out.
 
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c) The air does no work in expanding into the additional chamber since there is no air in it. The container is also isolated. This means that the energy lost is zero and the temperature will therefore stay the same. This is contradictory to everyday experience since a gas normally cools when it expands, but in this case the expansion occurs at no cost. The pV product will therefore be constant.
 
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andrevdh said:
c) The air does no work in expanding into the additional chamber since there is no air in it. The container is also isolated. This means that the energy lost is zero and the temperature will therefore stay the same. This is contradictory to everyday experience since a gas normally cools when it expands, but in this case the expansion occurs at no cost. The pV product will therefore be constant.

Yeah, I messed that up and got a weird number because I kept thinking that any gas that expands must cool. Mathematically,

<br /> Energy of the gas at equilibrium = \Delta_U = mc\Delta_T<br />

Since there is no change in energy, \Delta_U=0 and therefore

mc\Delta_T = 0

Since the mass m and specific heat of the gas cannot be 0,

\Delta_T = 0 and therefore T_{before} = T_{after}

Only realized that after the solution was given out. :biggrin:
 
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