Specific enthelpies of the streams

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Discussion Overview

The discussion revolves around the determination of specific enthalpies for various streams in a system involving NaOH solutions and steam. Participants explore the conditions under which specific enthalpies can be identified, including the need for temperature and pressure data, as well as the composition of the solutions. The scope includes theoretical considerations and practical applications related to enthalpy calculations in chemical engineering contexts.

Discussion Character

  • Homework-related
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants note that only the specific enthalpy for stream F can be found from literature values, while others express uncertainty about the specific enthalpies of streams S, V1, C1, C2, and V2 due to unknown temperatures.
  • It is mentioned that the specific enthalpies of streams F1 and F2 are unknown because the composition of NaOH is not provided.
  • One participant suggests that specific enthalpy for stream S can be interpolated from a pressure table, while others discuss the validity of assuming temperatures for streams V1 and V2.
  • There is a question about whether the temperatures and pressures of streams C1 and C2 should match those of V1 and V2, leading to further discussion about the role of steam in heating the NaOH solution.
  • Some participants clarify that when steam condenses at constant pressure, its temperature remains constant, which is acknowledged by others.
  • There are inquiries regarding the boiling point of a 10w/w% NaOH solution and its relation to the boiling temperatures of streams F, F1, and F2.

Areas of Agreement / Disagreement

Participants express differing views on the assumptions regarding temperatures and pressures for certain streams, particularly C1 and C2. There is no consensus on the validity of these assumptions, and the discussion remains unresolved regarding the specific enthalpies of these streams.

Contextual Notes

Participants highlight limitations in their calculations due to unknown temperatures and pressures, as well as the need for specific composition data for NaOH solutions. The discussion reflects a reliance on assumptions that may not be universally accepted.

Janiceleong26
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Homework Statement


Ass 2 2162.PNG
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part b.PNG

Homework Equations

The Attempt at a Solution


I have identified that only the specific enthalpy for stream F can be found from literature values, whereas the specific enthalpy of other streams are unknowns.

The specific enthalpy of streams S, V1, C1, C2 and V2 are unknowns because the temperature is unknown. On the other hand, specific enthalpy of streams F1 and F2 are unknown because the composition of NaOH is unknown.

May I know if I am correct?
 
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Janiceleong26 said:

Homework Statement


View attachment 211988 View attachment 211990
View attachment 211989

Homework Equations

The Attempt at a Solution


I have identified that only the specific enthalpy for stream F can be found from literature values, whereas the specific enthalpy of other streams are unknowns.

The specific enthalpy of streams S, V1, C1, C2 and V2 are unknowns because the temperature is unknown. On the other hand, specific enthalpy of streams F1 and F2 are unknown because the composition of NaOH is unknown.

May I know if I am correct?
Please tell us your rationale for arriving at these conclusions. Also, let's see the charts.
 
Chestermiller said:
Please tell us your rationale for arriving at these conclusions. Also, let's see the charts.

I just realized that I can get the specific enthalpy of stream S at 3.5 bar, by interpolating from 3.4 bar to 3.6 bar from from this table:
Table1: Properties of saturated steam: Pressure table
IMG_6924.JPG
For stream F, I can obtain the specific enthalpy from these charts:
IMG_6925.jpg

Chart1: Enthalpy of NaOH solution given mixture boiling temperature and mass fraction.

IMG_6926.jpg

Chart2: Boiling temperature of an aqueous solution of NaOH given the mass fraction and temperature of the boiling water.

For streams V1 and V2, I assumed that the temperature of the steam is 100 degC, or assume that the pressure is the same as the evaporator (50kPa) so I can find it from the literature values, though I'm not sure if my assumption is valid.

For streams F1 and F2, the specific enthalpies can't be found because we don't know how much of steam is evaporated and so we don't know the w/w% of NaOH solution in these streams.

However, can the specific enthalpies of streams C1, C2 be found? The temperature and pressure of these streams are not known so I'm guessing we can't unless we assume the pressure of C1 is 50kPa, but I'm not sure if this assumption is valid.
 
Last edited:
To know the specific enthalpies of streams C1 and C2, you need to know their temperatures and pressures. But shouldn't these be the same as the temperatures and pressures of V1 and V2?
 
Chestermiller said:
To know the specific enthalpies of streams C1 and C2, you need to know their temperatures and pressures. But shouldn't these be the same as the temperatures and pressures of V1 and V2?
I thought the steam provides heat to the evaporator to heat the NaOH solution? So the temperature of the condensate is not the same as V1?
 
Janiceleong26 said:
I thought the steam provides heat to the evaporator to heat the NaOH solution? So the temperature of the condensate is not the same as V1?
You are aware that, when steam condenses, if its pressure stays constant, its temperature is constant, correct?
 
Chestermiller said:
You are aware that, when steam condenses, if its pressure stays constant, its temperature is constant, correct?
Oh I see, okay thanks so much!
 
Chestermiller said:
To know the specific enthalpies of streams C1 and C2, you need to know their temperatures and pressures. But shouldn't these be the same as the temperatures and pressures of V1 and V2?

Sry one more thing.. how do we know the boiling point of water at 10w/w% NaOH solution?
 
Janiceleong26 said:
Sry one more thing.. how do we know the boiling point of water at 10w/w% NaOH solution?
Chart 2
 
  • #10
Hi @Chestermiller, I am having some doubts on the temperature of the first evaporator.

Assuming the temperature of the first evaporator is the same as the boiling temperature of the NaOH solution..
Is the temperature of the first evaporator equals to the boiling temperature of stream F or F1?
Also, is 60 deg C the boiling temperature of F2?
 
Last edited:
  • #11
Janiceleong26 said:
Hi @Chestermiller, I am having some doubts on the temperature of the first evaporator.

Assuming the temperature of the first evaporator is the same as the boiling temperature of the NaOH solution..
Is the temperature of the first evaporator equals to the boiling temperature of stream F or F1?
F1
Also, is 60 deg C the boiling temperature of F2?
yes
 
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  • #12
Chestermiller said:
F1

yes
Thanks
 

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