Standard deviation of V_x of He gas

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SUMMARY

The discussion centers on calculating the standard deviation of the velocity component \( v_x \) for helium gas. The correct formula for the standard deviation is established as \( \sigma_{v_x} = \sqrt{E(v_x^2) - (E(v_x))^2} \), with the conclusion that \( \sigma_{v_x} = v_{rms} \) when the mean velocity \( E(v_x) \) is zero. The participants clarify the use of expectancy notation \( E(X) \) and correct arithmetic errors related to the root mean square speed calculation. The final correct value for the root mean square speed is determined to be approximately 786 m/s.

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  • Understanding of statistical mechanics concepts, particularly standard deviation and root mean square speed.
  • Familiarity with the notation of expectancy in probability theory, specifically \( E(X) \) and \( \).
  • Knowledge of the kinetic theory of gases and its equations, including the relationship between temperature and molecular speed.
  • Basic proficiency in LaTeX for mathematical expressions.
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  • Study the derivation of the root mean square speed for different gases using the ideal gas law.
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Pushoam
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Homework Statement

Homework Equations

The Attempt at a Solution



## \frac 1 2 m<v_x^2> =\frac 1 2 k_BT ,

\\ \sqrt{ <v_x^2>} = 556~ m/s ## So, I guess that the standard deviation should be less than rms speed.

So, the option is (a)

## \left< ax + b \right> = a\left<x\right> + b ##

So, ## \left< v_x^2 - <v_x^2> \right> = \left< v_x^2\right> - \left< v_x^2\right> = 0 ##

Is this correct?
[/B]
 
Last edited:
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I think it your last statement, you are attempting to write ## \sigma^2=E(X^2)-(EX)^2 ##. If that is the case, and you are saying ## EX=0 ## , yes, it is correct. Please put in the mass and temperature so that we can check your arithmetic. For the final answer, the standard deviation, ## \sigma_{v_x}=\sqrt{E(v_x)^2}=v_{x \, rms} ##. Also, the statement of the problem is incomplete. The available answers did not show up.
 
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The question is not showing in the OP. So, posting it again.
upload_2017-12-26_22-4-13.png

Charles Link said:
I think it your last statement, you are attempting to write ## \sigma^2=E(X^2)-(EX)^2 ##. I
I didn't understand what you mean by the above line. Please explain the symbol EX and so on.
 

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Pushoam said:
The question is not showing in the OP. So, posting it again.
View attachment 217447

I didn't understand what you mean by the above line. Please explain the symbol EX and so on.
In probability theory, the ## E ## means expectancy. ## EX ## is the same thing as ## <X> ##.
 
Pushoam said:

So, ## \left< v_x^2 - <v_x^2> \right> = \left< v_x^2\right> - \left< v_x^2\right> = 0 ##

In the above statement, as ## < v_x ^2> ## is constant, I am taking it out of ## \left< v_x^2 - <v_x^2> \right>## and hence I got ## \left< v_x^2 - <v_x^2> \right> = \left< v_x^2\right> - \left< v_x^2\right> = 0 ##.
But, this way I will always get 0 standard deviation. So, something is wrong with it. Right?
 
Pushoam said:
In the above statement, as ## < v_x ^2> ## is constant, I am taking it out of ## \left< v_x^2 - <v_x^2> \right>## and hence I got ## \left< v_x^2 - <v_x^2> \right> = \left< v_x^2\right> - \left< v_x^2\right> = 0 ##.
But, this way I will always get 0 standard deviation. So, something is wrong with it. Right?
The equation correctly reads ## \sigma^2_{v_x}=<v_x^2>-<v_x>^2 ##. ## \\ ## Editing: This comes from ## \sigma^2_{v_x}=<(v_x-<v_x>)^2> ##. And I think your arithmetic in the OP is incorrect.
 
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## \sqrt{ <v_x^2>} = \sqrt{ \frac { k_BT = 4.14 * 10^{-21}}{m=4* m_p = 6.69 * 10^{-27}}}= 786~ m/s ##

Is this correct?
 
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Yes. Very good. Round that off and (d) becomes the correct answer. See also my edited additions to post 6.
 
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Charles Link said:
See also my edited additions to post 6.
I reloaded the page three times. Still, no edition to post #6 is shown.
What I get in post # 6 is:
Charles Link said:
The equation correctly reads ## \sigma^2_{v_x}=<v_x^2>-<v_x>^2 ##. This comes from ## \sigma^2_{v_x}=<(v_x-<v_x>)^2> ##. And I think your arithmetic in the OP is incorrect.
 
  • #10
Pushoam said:
I reloaded the page three times. Still, no edition to post #6 is shown.
What I get in post # 6 is:
I didn't use the word "edit". Let me put it in there for clarity. After I wrote the original post, I came back a couple of minutes later and added the last two sentences.
 
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  • #11
Thanks.
 
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  • #12
Now I understood.

## \sigma_{v_x} = \sqrt{ \left< (v_x - \left <v_x \right >)^2 \right> = \left < v_x^2 \right > – 2 \left < v_x \right >^2 + \left < v_x \right >^2 = \left < v_x^2 \right > – \left < v_x \right >^2 }##

Since , ## \left < v_x \right > = 0 ##

## \sigma_{v_x} = v_{rms} ##
 
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  • #13
Very good. :) (You need a parenthesis { } around v_x in the subscript of ## \sigma_{v_x} ##. Then your Latex will work.)
 
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