Statistical thermodynamics- ideal gases mixture (Reif 3.6)

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SUMMARY

The discussion centers on a thermodynamics problem involving a glass bulb containing air at 1 atmosphere pressure, placed in a helium-filled chamber also at 1 atmosphere. Due to the glass's permeability to helium, the final pressure inside the bulb will reach 2 atmospheres once equilibrium is attained. This conclusion is based on the principle that the partial pressure of helium inside the bulb will equal the external helium pressure, leading to a total pressure of 2 atmospheres when combined with the air pressure already present.

PREREQUISITES
  • Understanding of ideal gas laws
  • Familiarity with partial pressure concepts
  • Knowledge of gas permeability and diffusion principles
  • Basic principles of thermodynamic equilibrium
NEXT STEPS
  • Study the ideal gas law and its applications in thermodynamics
  • Learn about Dalton's Law of Partial Pressures
  • Research gas permeability and its effects on gas mixtures
  • Explore thermodynamic equilibrium concepts in closed systems
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This discussion is beneficial for students and professionals in physics, chemistry, and engineering, particularly those focusing on thermodynamics and gas behavior in mixtures.

sergiopinilla
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A glass bulb contains air at room temperature and at a pressure of 1 atmosphere. It is
placed in a chamber filled with helium gas at 1 atmosphere and at a room temperature. A
few months later, the experimenter happens to read in a journal article that the particular
glass of which the bulb is made is quite permeable to helium, although not to any other
gases. Assuming that equilibrium has been attained by this time, what gas pressure will the
experimenter measure inside the bulb when he goes back to check? Please help, the solutions manual says its 2 atmospheres but I don't really know how to start.
 
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sergiopinilla said:
A glass bulb contains air at room temperature and at a pressure of 1 atmosphere. It is
placed in a chamber filled with helium gas at 1 atmosphere and at a room temperature. A
few months later, the experimenter happens to read in a journal article that the particular
glass of which the bulb is made is quite permeable to helium, although not to any other
gases. Assuming that equilibrium has been attained by this time, what gas pressure will the
experimenter measure inside the bulb when he goes back to check? Please help, the solutions manual says its 2 atmospheres but I don't really know how to start.

You have to assume that the volume of helium is much, much greater than the volume of the bulb. With a membrane permeable to only helium, what is the relationship between the partial pressure of helium inside the bulb to the helium pressure outside the bulb (ie in the helium chamber surrounding the glass bulb)?

AM
 
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