JustinLevy said:
Hmm... I'm not quite understanding.
How can particle number hold non-perturbatively? I thought we could only discuss particles as "free states" and that is why for calculations things come in from infinity, interact, and then go off to infinity.
What you describe is the general principle of scattering, which is a nonperturbative notion. Perturbation theory comes in only when you want to calculate scattering cross sections numerically.
JustinLevy said:
But with field theory, isn't it no longer well defined the number of electrons and positrons and photons that are in a hydrogen atom?
A neutral hydrogen atom consists of exactly one proton and one electron, and an indeterminate number of (virtual) photons and additional (virtual) particle-antiparticle pairs. The latter, being unobservable, are usually not counted but occasionally talked about (often only by people like kexue who mistakenly believe that that would explain a lot).
JustinLevy said:
Isn't that part of the idea behind the lamb shift?
No. That comes from the contribution of a single photon to the energy levels of the hydrogen atom.
JustinLevy said:
if you could explain a bit more in depth the concept of particles in field theory (especially in bound systems) it would be much appreciated.
Particles are the asymptotic states of definite momentum. Elementary particles are those particles that can be related to the fields occurring in the action.
In QED, the electron number operator N is just a particular operator in field theory that happens to have integral eigenvalues only. An eigenstate of N with the eigenvalue n>0 is interpreted as an n-electron state, an eigenstate of N with the eigenvalue n<0 is interpreted as an n-positron state, and an eigenstate of N with the eigenvalue zero
as a neutral state. An example of a neutral state is that formed by a positron colliding
with an electron (with a small chance of annihilation); such a state is nonlocal since in the past the positron and the electron were far apart.
Sometimes, especially by people like kexue, localized neutral states are identified with the fluctuating vacuum, in which virtual particles can pop in and out of existence for a
extremely short time. But serious people call vacuum only the ground state of a field theory (which is neutral). That state is completely inert. Nothing ever happens.
JustinLevy said:
Electrons have an internal degree of freedom, so there should be two spacings, no?
The number operator - unlike the Hamiltonian - has a purely discrete, integral, equispaced spectrum, in which the internal degrees of freedom are degenerate.
JustinLevy said:
I guess I just never really understood in what limits we can still discuss "particles" in field theory.
The right limit is usually called the limit of geometric optics, although it is usually discussed only for photons (hence the name).
JustinLevy said:
I recently ordered Zee's "Field Theory in a Nutshell", since I tried reading Srednicki's book and was really struggling to get a hold of what the meaning of any of the mathematical manipulations were. Do you think that is an okay place to start, or can you suggest a better book to pedagogically bridge from particle quantum mechanics to quantum field theory?
No single source is good to start. You need to try reading at different levels, and often go in cycles. It takes a long time to understand QFT, as there are deeper and deeper levels of understanding. So if you have understood something on some level, step back and review the more elementary stuff to see whether what you learned sheds new light on what you knew already - it often will.
If you are not afraid of the math involved, Volume 1 of Weinberg is the clearest.
But probably you need other books on the side...