Temperature change (first law of thermodynamics)

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SUMMARY

The forum discussion centers on the first law of thermodynamics, specifically the relationship defined by the equation Cp * (δT/δt) = (δQ/δt), where Cp represents specific heat capacity, T is temperature, Q is heat, and t is time. Participants clarify that temperature can continue to rise even when the rate of heat flow (dQ/dt) is negative, particularly during the diurnal cycle of air temperature. The distinction between Eulerian temperature changes and Lagrangian energy flux density is emphasized, highlighting that temperature is a local change while energy flux can vary along its path.

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  • Understanding of the first law of thermodynamics
  • Familiarity with specific heat capacity (Cp)
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jones123
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Hi,

From the first law of thermodynamics it follows:

Cp * (δT/δt) = (δQ/δt)
where Cp = specific heat capacity, T = temperature, Q = heat, t = time

From this formula, you would derive that temperature keeps on increasing as long as dQ/dt > 0. But if you, for example, look at the idealized diurnal evolution of air temperature, it can be seen that the temperature keeps on increasing until its maximum value, despite the fact that there is net heat loss (dQ/dt < 0 for example between noon and 4h where the area between both curves becomes smaller)...

It seems that on the figure here the temperature keeps on rising as long as the value of Q itself > 0 but that doesn't necessarily mean that dQ/dt has to be > 0, right? Is my reasoning wrong or how can this correctly be explained with formulas?

Thanks already!

DailyT.jpg
 
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The sun doesn't heat the air, it heats the ground.
 
jones123 said:
Hi,

From the first law of thermodynamics it follows:

Cp * (δT/δt) = (δQ/δt)
where Cp = specific heat capacity, T = temperature, Q = heat, t = time

From this formula, you would derive that temperature keeps on increasing as long as dQ/dt > 0. But if you, for example, look at the idealized diurnal evolution of air temperature, it can be seen that the temperature keeps on increasing until its maximum value, despite the fact that there is net heat loss (dQ/dt < 0 for example between noon and 4h where the area between both curves becomes smaller)...

It seems that on the figure here the temperature keeps on rising as long as the value of Q itself > 0 but that doesn't necessarily mean that dQ/dt has to be > 0, right? Is my reasoning wrong or how can this correctly be explained with formulas?

Thanks already!

View attachment 205308
dQ/dt is the current rate of solar heat flow. So throughout the day, current rate of solar heat flow is positive. The graph says Energy Rate, not cumulative amount of energy.
 
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Chestermiller said:
dQ/dt is the current rate of solar heat flow. So throughout the day, current rate of solar heat flow is positive. The graph says Energy Rate, not cumulative amount of energy.
Oh I get it,

it's just that the temperature change is Eulerian (a local change at a fixed position) whereas the energy flux density is Lagrangian (it crosses the air on its path while having a negative or positive value).
 
jones123 said:
Oh I get it,

it's just that the temperature change is Eulerian (a local change at a fixed position) whereas the energy flux density is Lagrangian (it crosses the air on its path while having a negative or positive value).
Both are as reckoned by a "stationary" observer on the surface of the earth.
 

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