Texas Fertilizer Plant Explosion ?

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A fire at a Texas fertilizer plant, where ammonia is produced and stored, led to a massive explosion. The chemical reactions involved are primarily linked to ammonia production via the Haber process, where nitrogen and hydrogen combine to form ammonia. Three potential causes for the explosion were discussed: the explosion of a hydrogen tank, the possibility of heat from the fire driving the ammonia reaction backward to produce hydrogen, and the combustion of ammonia itself. However, the most likely cause identified was the explosion of ammonium nitrate, a common occurrence in such incidents. It is suggested that the fire was initiated by an ammonia leak, which, combined with ammonium nitrate, heated a tank of liquid ammonia, resulting in the explosion. Witnesses reported a strong ammonia smell before the explosion, indicating a fuel-air type explosion involving ammonia and oxygen, rather than significant buildup of ammonium nitrate decomposition products.
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It started as a fire at a Texas fertilizer plant where ammonia is produced and stored. Then
a massive explosion. What happened chemically ? Three possibilities : Ammonia produced
by the Haber process. N2 + 3H2 --> 2NH3 -92 kJ/m
1. a hydrogen tank exploded.
2. With heat from the initial fire could above reaction been driven to left producing H2 ?
3. Combustion/explosian of ammonia: 4NH3 + 3O2 --> 2N2 + 6H2O -1267kJ/m
 
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I think it was a fire started after an ammonia leak, supported by the ammonium nitrate, which heated a large tank of liquid ammonia to the point of explosion. It was reported that there was a strong smell of ammonia just before the event. Typical fuel-air explosion boosted by the decomposition products of ammonium nitrate. From the videos I've seen just before the explosion, it is unlikely that the ammonium nitrate decomposition products (mostly NOx compounds) ever built up significant concentrations before they burned off. Probably just a fuel-air type explosion... ammonia plus oxygen.
 
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