The direction of electric dipole moment of water molecule

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Discussion Overview

The discussion revolves around the differences in the representation of the electric dipole moment of the water molecule as seen in various sources, including textbooks and videos. Participants explore the implications of these differences in directionality and labeling, as well as the definitions used in physics and chemistry.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants note a discrepancy between the dipole moment representations in textbooks and online videos, questioning why they differ.
  • It is mentioned that both representations show the dipole moment as positive towards the hydrogen atoms and negative towards the oxygen atom, but the direction of the arrow differs.
  • One participant explains that the usual representation is derived from the definition of the dipole moment, but questions remain about the alternative representation in the video.
  • There is a suggestion that the direction of the dipole moment might be represented differently in physics compared to chemistry, prompting further inquiry into this claim.
  • Participants discuss the placement of the origin of the coordinate system for drawing position vectors, indicating that it may not affect the representation of the dipole moment.
  • One participant points out that the definition formula for the dipole moment appears consistent across disciplines, despite the differences in representation.

Areas of Agreement / Disagreement

Participants express differing views on the representation of the dipole moment, with no consensus reached on the reasons for the discrepancies or the implications of the differing representations.

Contextual Notes

There are unresolved questions regarding the implications of the differing representations in physics and chemistry, as well as the choice of coordinate system origins for vector representation.

AdrianMachin
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I was watching a video explaining how microwave ovens work when I found that there is a difference between my physics textbook and online images of the electric dipole moment of the water molecule, as well as the one shown in the video.

View attachment 195065

Why do they differ?
 
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What is the difference?
 
Dale said:
What is the difference?

The direction shown for the dipole moment is different.
 
They both show the dipole moment as positive towards the H and negative towards the O. One draws the arrow from positive to negative, but they both are labeled correctly.
 
The direction shown in your book is the usual one, as is derived from the definition of the dipole moment ## \vec{p}=\sum q \vec{r} ##
where ## \vec{r} ## is the position vector of the charge q.
Why they show it the other way in that video is hard to say, especially without watching the video.
 
nasu said:
The direction shown in your book is the usual one, as is derived from the definition of the dipole moment ## \vec{p}=\sum q \vec{r} ##
where ## \vec{r} ## is the position vector of the charge q.
Why they show it the other way in that video is hard to say, especially without watching the video.
Where do you place the origins of your coordinate system for drawing ## \vec{r} ## vectors?
Somebody said that the direction of the dipole moment in Physics is reverse than what it is in Chemistry, is it true?
Dale said:
They both show the dipole moment as positive towards the H and negative towards the O. One draws the arrow from positive to negative, but they both are labeled correctly.
Aren't they vectors? So how can we reverse the direction of a vector and not changing it?
 
Dale said:
One draws the arrow from positive to negative, but they both are labeled correctly.

That is what the OP is asking about, the differently drawn arrows.
 
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AdrianMachin said:
Where do you place the origins of your coordinate system for drawing ## \vec{r} ## vectors?
Somebody said that the direction of the dipole moment in Physics is reverse than what it is in Chemistry, is it true?
It looks like indeed in chemistry they choose to represent the dipole moment vector pointing from positive to negative even though the definition formula looks to be the same as the one used in physics.
See here for example (caption to figure 1.1)
https://chem.libretexts.org/Core/Ph...tomic_and_Molecular_Properties/Dipole_Moments

And it does not matter where you place the origin of the coordinate system. The simplest choice is to place it between the two charges but is just the simplest not the only option.
 
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