ECI is a pretty standard term. It is non-rotating and approximately inertial. The surface of the earth would be an earth-fixed frame, sometimes ECEF for earth centered earth fixed frame. It is non-inertial.More explicitly and correctly, according to SR clocks synchronized in the momentarily co-moving inertial frame (MCIF) of any earth clock will be unsynchronized in the ECI frame because those clocks are moving relative to the ECI frame.
This is the relativity of simultaneity. Two inertial frames moving with respect to each other (like the ECI and the MCIF) disagree on simultaneity.
Note that the ECEF frame is a non-inertial frame, so that statement doesn't apply. The ECEF frame is designed to have the same simultaneity as the ECI frame. So clocks synchronized in the non-inertial ECEF frame will also be synchronized in the ECI frame but not in their own MCIFs.The GPS system doesn't interact with any system of clocks that are synchronized in the MCIF of any earth clocks. So why would that "unsynchronization" matter? The earth clocks in the GPS use the ECI time, not the synchronization of their MCIF. In fact, many of the earth clocks don't even measure their own time, they simply use multiple signals from the space clocks to calculate the ECI time at their location. In that sense, they aren't even actually clocks.