Thermally Stable Materials for Selective Oxygen Trapping and Manipulation

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A discussion on finding a thermally stable material for selective oxygen gathering highlights various options, including metals and liquids. While many metals can oxidize and absorb oxygen, the focus is on the ability to reverse this process using an electrical current. Commercial oxygen absorbers typically use finely powdered iron, while molten silver can also dissolve oxygen. However, to effectively move absorbed oxygen through the application of electric current, an oxygen ionic conductor is necessary, with zirconia being a common example, often stabilized with other oxides and used in automotive oxygen sensors. This material operates at high temperatures. The conversation raises the question of whether a metal can absorb oxygen and then release it through electrical stimulation.
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Hello!

I am looking for a thermally stable material that will gather oxygen from air selectively.

I suppose many metals can do that? And oxidise? Or maybe liquids?

However, I want to apply an electrical current and either reverse the binding of oxygen or move the bound oxygen across the surface or the material itself.

Can you help me do this?

Thanks!
 
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Many metals and non-metals can chemically react with oxygen in the air. Commercial oxygen absorbers contain just finely powdered iron.
Molten silver dissolves oxygen too.
However, if you want to move absorbed oxygen by applying electric current, you need oxygen ionic conductor.
The most common is zirconia, often stabilized with addition of another oxide. It is used in automotive oxygen sensors.
It requires high temperature for operation.
 
Thanks Henry, very interesting.

Can we have a metal absorb oxygen and then release it by electric current?
 
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