How Do You Find Entropy for a Material Given Specific Equations?

In summary, to find the entropy for a material given by U=C1PV2 and PV2=C2T, use the equation dU=TdS-PdV and isolate for dS. Then, apply the given formulas for the material and integrate to find the entropy. It is important to note that both equations require certain conditions on state variables.
  • #1
lifeonfire
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Homework Statement



For a material given by U=C1PV2 and PV2=C2T
Find the entropy

Homework Equations



dS/dU = 1/T; dU/dV = -P

I don't know if I require anything else

The Attempt at a Solution



So from 2 equations I got U = C1
C2T

But dU/dT is not equal to S. Which equation do I use to get the entropy? I was thinking of using F = U-TS. Which will give F = C1PV2 - TS And then doing dF/dT but then I didn't use the 2nd condition at all.

What am I missing?
 
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  • #2
Hi lifeonfire! :smile:

Your relevant equations are not always true, the first requires V to remains constant, while the second requires S to remain constant.

For reversible processes, the equation dU=TdS-PdV is true without conditions on state variables.
From this you can isolate dS, apply the formulas given for your material, and integrate.
 

FAQ: How Do You Find Entropy for a Material Given Specific Equations?

1. What is entropy and why is it important in thermodynamics?

Entropy is a measure of the disorder or randomness in a system. In thermodynamics, it is important because it helps us understand the direction of energy flow and the efficiency of energy conversion processes.

2. How is entropy related to the second law of thermodynamics?

The second law of thermodynamics states that the total entropy of a closed system always increases over time. This means that energy tends to spread out and become more disordered. Entropy is directly related to this law as it quantifies the amount of disorder in a system.

3. How do you calculate entropy in a thermodynamic system?

The entropy of a thermodynamic system can be calculated using the equation S = Q/T, where S is entropy, Q is heat transferred, and T is temperature. Alternatively, it can also be calculated using statistical mechanics methods, which take into account the microstates of a system.

4. Can entropy be decreased in a system?

According to the second law of thermodynamics, the total entropy of a closed system cannot decrease. However, within a system, the entropy of one part can decrease as long as the overall entropy of the system increases. This is known as local entropy decrease.

5. How does entropy affect the efficiency of energy conversion processes?

Entropy plays a crucial role in the efficiency of energy conversion processes. In general, the higher the entropy of a system, the lower its efficiency in converting energy into useful work. This is because a higher level of disorder means more energy is wasted as heat instead of being converted into work.

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