Thermodynamics proving cp/cv = kt/ks

In summary, the equation cp/cv = kt/ks, also known as the adiabatic relation, is a fundamental equation in thermodynamics that describes the relationship between specific heats at constant pressure and constant volume, and the ratio of thermal conductivity to specific heat. It is derived from the first and second laws of thermodynamics and can be used to analyze the behavior of gases and confirm the validity of thermodynamic principles. Although it is applicable to all ideal gases, real gases may deviate slightly from this equation. It is used in practical applications such as heat engine design and atmospheric process analysis, but has limitations as it assumes ideal conditions and can only be used for gases.
  • #1
Chronos000
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Homework Statement



at some point in my derivation I get to the following line:

cp/cv = (dS/dP)T(dP/dT)S / (dS/dV)T(dV/dT)S

I think this equals (dS/dP)T(dS/dV)P / (dP/dT)V(dV/dT)S

- from applying maxwells relations.
but my book says it is in fact the following:

(dS/dP)T(dV/dS)T / (dV/dT)S(dT/dP)S

I haven't a clue how they are doing this
 
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  • #2
Aren't they just using [itex]1/(dX/dY)_Z=(dY/dX)_Z[/itex]?
 

1. What does the equation cp/cv = kt/ks represent?

The equation cp/cv = kt/ks is known as the adiabatic relation, which describes the relationship between specific heats at constant pressure (cp) and constant volume (cv), and the ratio of thermal conductivity (kt) to specific heat (ks). It is a fundamental equation in thermodynamics that helps to understand the behavior of gases under different conditions.

2. How does this equation prove thermodynamics?

The adiabatic relation is derived from the first and second laws of thermodynamics, which are fundamental principles in the study of energy and its transformations. By using this equation, we can analyze the behavior of gases and their energy changes, and it helps to confirm the validity of thermodynamic principles.

3. Is this equation applicable to all gases?

Yes, the adiabatic relation is applicable to all gases, as long as they are considered ideal gases. This means that the gases do not have any intermolecular forces and their molecules have negligible volumes compared to the container they are in. Real gases may deviate slightly from this equation due to their non-ideal behavior, but it is still a useful approximation in many cases.

4. How is this equation used in practical applications?

The adiabatic relation is used in various practical applications, such as in the design of heat engines and turbines, as well as in the analysis of atmospheric processes. It is also used in the study of thermodynamic properties of gases, and in the calculation of specific heats and thermal conductivity.

5. Are there any limitations to this equation?

While the adiabatic relation is a useful tool in understanding the behavior of gases, it does have some limitations. It assumes that the gases are ideal and that the processes are reversible. In real-world situations, these conditions may not always be met, and therefore the equation may not accurately represent the behavior of the gases. Additionally, it is only applicable to gases and cannot be used for other substances like liquids or solids.

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