Thermodynamics: why is freon a "good" coolant?

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    Coolant Thermodynamics
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SUMMARY

Freon and acetone are effective coolants due to their ability to vaporize and condense at specific temperature ranges, rather than their heat capacity. While water has a higher specific heat capacity, it is not suitable for refrigeration applications because it does not vaporize and condense efficiently within the required temperature limits. The ideal refrigerant must vaporize around 40°F and condense near 140°F, allowing for effective heat transfer in cooling systems. This property is crucial for the functionality of air conditioners and similar heat exchange systems.

PREREQUISITES
  • Understanding of phase changes in fluids
  • Knowledge of thermodynamic principles
  • Familiarity with refrigeration cycles
  • Basic chemistry of refrigerants
NEXT STEPS
  • Research the thermodynamic properties of refrigerants, focusing on vaporization and condensation temperatures
  • Explore the refrigeration cycle and its components, including evaporators and condensers
  • Study the environmental impact and efficiency of various refrigerants, including Freon and propane
  • Investigate alternative coolants and their applications in modern HVAC systems
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Engineers, HVAC professionals, and students studying thermodynamics or refrigeration systems will benefit from this discussion, particularly those interested in the selection and application of effective coolants.

iScience
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I always thought that a working substance / coolant with a high heat capacity is better since it can take in more thermal energy. why then are some of the most common heat exchange fluid chemicals ones with low heat capacities?

acetone and freon for example, are commonly used heat exchange fluids. But what makes them better candidates than water which has a higher specific heat capacity?
 
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Is there another physical property that can be/is used for refrigeration/heat transfer?
 
If you think about freon in a cooling system, then it is not a passive "heat exchange" fluid. It is supposed to evaporate easily in order to "capture" the heat from the hot object. The vapors are then condensed somewhere else to release the heat. I suppose acetone is used in a similar way. Like in the "drinking bird" toy.

Edit
Oh, bystander's post was not up when I wrote.
 
oh right, forgot about that other half. so, low latent heat values for fusion and vaporization.
 
iScience said:
, low high latent heat values for fusion and vaporization
 
iScience said:
oh right, forgot about that other half. so, low latent heat values for fusion and vaporization.
Actually, no, it isn't the latent heat of vaporization or fusion (not fusion at all). It is the temperature of vaporization. Air conditioners have specific temperature ranges for their heat source and sink, so the working fluid must be capable of doing its phase changes near those temperatures. So what is needed is a fluid that will vaporize at about 40F and condense at 140F, at reasonable pressures. Indeed, the same property that makes propane a useful stored BBQ grill fuel makes it a good refrigerant!

A similar reasoning is why steam is good for heating.
 

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