Thermoelectric devices and entropy

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Discussion Overview

The discussion revolves around the operation of thermoelectric devices in relation to the laws of thermodynamics, particularly the second law. Participants explore how these devices convert heat into electrical current and the conditions necessary for this process, including the requirement of a temperature difference.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions how thermoelectric devices can operate without violating the second law of thermodynamics, given that adding heat to a wire is said to not produce a current.
  • Another participant notes that thermoelectric devices require a temperature difference between two plates to function effectively.
  • A participant expresses confusion about why adding heat to a wire does not yield a current, suggesting that it seems similar to the operation of thermoelectric devices.
  • One participant explains that heating one end of a wire initially creates a current, but equilibrium is quickly reached, preventing sustained current flow in an open circuit.
  • Another participant raises the concern that thermoelectric generators (TEGs) would eventually reach thermal equilibrium, questioning the sustainability of the temperature difference necessary for their operation.
  • A participant clarifies that the second law does not prohibit heat from producing electrical work but rather sets an upper limit on the efficiency of such processes, indicating that thermoelectric devices operate below this limit.
  • One participant challenges the understanding of temperature difference, asking for clarification on the cold reservoir in the context of thermoelectric devices and how heat flows to it.

Areas of Agreement / Disagreement

Participants express differing views on the mechanisms by which thermoelectric devices operate and the implications of the second law of thermodynamics. There is no consensus on the specifics of how these devices function in relation to thermal equilibrium and the necessary conditions for generating current.

Contextual Notes

Participants highlight the importance of understanding the roles of temperature differences and reservoirs in thermoelectric processes, indicating that assumptions about these factors may influence their arguments.

mrblanco
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Today in my thermodynamics class my professor spoke about how a process must satisfy the laws of thermodynamics in order to work. He gave an example of current going through a wire generating heat. (See attached picture) But he also talked about how adding heat to a wire and it generating a current would violate the 2nd law of thermodynamics. My question is, how does a thermoelectric device, which takes heat and turns it into a current, follow the 2nd law?
ImageUploadedByPhysics Forums1427315710.620976.jpg
 
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Because thermoelectric devices require there to be a temperature difference between two plates. Go look it up and see what you find.
 
I've looked it up and it seems to make sense, however, why would adding heat to a wire to produce a current not work? It seems like it would be the same process. If I'm adding heat then obviously there will be a temperature difference
 
If you heat one end of a wire, there is an initial current : the electrons run away to the other end as much as they can. But you very soon (seconds) get equilibrium because the first ones push back (- charged) the rest, which are left to bake in the heat (they actually don't mind that much). You can't have current in an open circuit, so you're left with a voltage.
 
Wouldn't that eventually happen in a TEG? The plates would eventually come to thermal equilibrium and there would no longer be a ΔT.
 
mrblanco said:
I've looked it up and it seems to make sense, however, why would adding heat to a wire to produce a current not work? It seems like it would be the same process. If I'm adding heat then obviously there will be a temperature difference
The second law doesn't prohibit heat from producing electrical work, it just puts an upper bound on the amount of work that cAn be done. Thermoelectric devices operate well below that limit.
 
mrblanco said:
I've looked it up and it seems to make sense, however, why would adding heat to a wire to produce a current not work? It seems like it would be the same process. If I'm adding heat then obviously there will be a temperature difference
A temperature difference between what and what? Obviously, the wire is the hot reservoir: where's the cold reservoir, how is heat flowing to it and how is your thermodynamic device getting in the way to harness/capture that flow?
 

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