Undergraduate Student Seeking Answers on Sustaining Entropy

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Discussion Overview

The discussion revolves around the concept of sustaining entropy at a constant level over time, particularly in the context of the second law of thermodynamics. Participants explore theoretical implications, practical limitations, and the distinctions between different types of systems.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests that a reversible reaction does not increase entropy, implying that machines using only reversible reactions could maintain constant entropy, though this approach is limited.
  • Another participant questions the precision of the entropy discussion, asking for clarification regarding the entropy of the universe versus that of a specific closed system.
  • Some participants argue that while it is impossible to keep the entropy of the entire universe constant, it may be feasible to maintain constant entropy in a carefully designed closed system, although practical non-idealities in macroscopic systems typically lead to increasing entropy.
  • A participant highlights a potential terminology issue between physicists and engineers regarding the definitions of "closed" and "isolated" systems, noting that under the engineering definition, entropy can decrease in certain processes.

Areas of Agreement / Disagreement

There is no consensus on the feasibility of sustaining entropy at a constant level, with participants presenting competing views on the definitions of systems and the implications of the second law of thermodynamics.

Contextual Notes

Participants express uncertainty regarding the definitions of closed and isolated systems, and the implications of these definitions on entropy behavior. There are also unresolved questions about the conditions under which entropy might remain constant.

TheoPan
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Hello everyone!

I am an undergraduate student from Greece in my first semester of Mechanical Engineering, but I am fascinated with physics. I've been studying some physics books from my university's library and reached the chapter of entropy. I understand the 2nd law of thermodynamics but what would happen if we could sustain entropy at the same level over time? Is it possible? Would it be possible in the future?

Thank you in advance!
 
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A reversible reaction is one that does not increase the entropy. A machine only using reversible reactions will keep the same entropy. But this really limits what you can do.
An irreversible reaction increases entropy. Your body has a bunch of irreversible reactions, so entropy overall will increase.
 
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Khashishi said:
A reversible reaction is one that does not increase the entropy. A machine only using reversible reactions will keep the same entropy. But this really limits what you can do.
An irreversible reaction increases entropy. Your body has a bunch of irreversible reactions, so entropy overall will increase.
Can you please state this more precisely, like, for example, with respect to the entropy of the universe rather than the entropy of a specific (closed) system?
 
I guess it depends on what the OP is asking. If they are asking if it's possible to keep the entropy of the whole universe at a fixed level, then the answer is no. But for a small, carefully designed closed system, the second law only prohibits the entropy from going down. It is allowed to stay at the same level. For a macroscopic sized system, there's always some non-idealities, so you can't really prevent entropy from increasing. As a MechE, you will certainly learn about adiabatic processes, which are idealizations, but they are useful to study since we can get close, and they teach us the fundamental limits on what is possible.
 
Khashishi said:
I guess it depends on what the OP is asking. If they are asking if it's possible to keep the entropy of the whole universe at a fixed level, then the answer is no. But for a small, carefully designed closed system, the second law only prohibits the entropy from going down. It is allowed to stay at the same level. For a macroscopic sized system, there's always some non-idealities, so you can't really prevent entropy from increasing. As a MechE, you will certainly learn about adiabatic processes, which are idealizations, but they are useful to study since we can get close, and they teach us the fundamental limits on what is possible.
I think that we have a bit of a terminology issue here. Physicists call a "closed system" one for which no mass enters or leaves, and no work or heat transfer takes place at the boundaries; however, this is what engineers refer to as an "isolated system." Engineers call a "closed system" one for which no mass enters or leaves, but for which work and heat transfer can take place at the boundaries. Under this engineering definition of a closed system, entropy can certainly decrease for certain processes.

Chet
 

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