Because, by definition, a cell is primitive if it contains exactly the smallest number of atoms possible (the smallest possible basis) from which the entire lattice can be constructed.
Once you have one possible primitive cell you can obtain others by cutting off a bit on one side and adding it on the opposite side. Obviously, this operation does not change the volume of the cell.
I am new to XPS Data analysis, and I have a .sle file that I got out of XPS Machine Software, and I am using CasaXPS to analyse the data. This software takes only .vms files. I want to convert the .sle to a .vms file for analysis. How or where can I do this? Any help on this will be deeply appreciated.