Understanding the Isothermal Process: Temperature and Internal Energy Explained

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Discussion Overview

The discussion centers around the isothermal process in thermodynamics, specifically addressing the relationship between temperature, internal energy, and heat transfer. Participants explore the implications of the isothermal condition on various equations and concepts, including the behavior of ideal gases and the application of specific heat equations.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant asserts that in an isothermal process, the change in temperature is zero, leading to a change in internal energy being zero, thus Q=W.
  • Another participant challenges the application of the equation Q=mc(delta T) in the context of the isothermal process, stating that it is not applicable for the system itself, but may apply to the surroundings.
  • A third participant points out that the assertion about internal energy being zero in an isothermal process is only true for ideal gases and may not hold for other systems.
  • One participant reiterates the explanation of how work done on or by the system affects heat transfer to maintain constant temperature, emphasizing the need for heat exchange during expansion or compression.

Areas of Agreement / Disagreement

Participants express differing views on the applicability of the equation Q=mc(delta T) and the conditions under which internal energy changes in isothermal processes. There is no consensus on the broader applicability of the zero change in internal energy statement beyond ideal gases.

Contextual Notes

Limitations include the specific conditions under which the statements about internal energy apply, as well as the dependence on the type of system being discussed (ideal gas versus other systems).

101nancyma
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Urgent!Isothermal process

Hi guys. i have a very short question. In an isothermal process, change is temperature is zero, so change in internal energy is zero, thus Q=W. The part that i am confused is that if Q=mc(deltaT) then should be a change in temperature in the isothermal process?
Thanks a lot
 
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Q = mc(delta T) is not the correct equation in this example for the system. It has already been stated that Q must equal W in an isothermal process.

Think of it this way, if the system is a piston and the piston is drawn up then the system should cool. To keep the system at a constant temperature, the system is heated with the same energy that is extracted through work. Likewise, if the system is compressed then the system will have to expel heat to maintain its temperature.

If the system were in some kind of medium (air, water, etc) then the equation Q=mc(delta T) can be used for the surroundings.

Hope this helps.
 


bucher said:
Q = mc(delta T) is not the correct equation in this example for the system. It has already been stated that Q must equal W in an isothermal process.

Think of it this way, if the system is a piston and the piston is drawn up then the system should cool. To keep the system at a constant temperature, the system is heated with the same energy that is extracted through work. Likewise, if the system is compressed then the system will have to expel heat to maintain its temperature.

If the system were in some kind of medium (air, water, etc) then the equation Q=mc(delta T) can be used for the surroundings.

Hope this helps.

I totally understand now..thanks a lot
 

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