I Vanadium oxide oxidation states binding energy -- unequal spacing

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Hello,
How come in XPS the binding energy gaps between oxidation states of vanadium oxide are not equally spaced? Is there a reason they are not all equally spaced?
Hello, How come in XPS the binding energy gaps between oxidation states of vanadium oxide are not equally spaced? Is there a reason they are not all equally spaced? V2+ (VO) 513.0 eV V3+ (V2O3) 515.6 eV V4+ (VO2) 516.0 eV V5+ (V2O5) 517.1 eV Many thanks
 
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Why would you expect them to be equally spaced? They’re in different chemical environments.
 
Hi. I have got question as in title. How can idea of instantaneous dipole moment for atoms like, for example hydrogen be consistent with idea of orbitals? At my level of knowledge London dispersion forces are derived taking into account Bohr model of atom. But we know today that this model is not correct. If it would be correct I understand that at each time electron is at some point at radius at some angle and there is dipole moment at this time from nucleus to electron at orbit. But how...

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