Zero velocity can occur at a single instant while acceleration remains non-zero, as demonstrated by a ball thrown upwards that momentarily stops at its peak height. Throughout its ascent and descent, the ball experiences constant downward acceleration due to gravity, even when its velocity is zero at the top. This concept can also be illustrated with other scenarios, such as a mass in a harmonic oscillator at maximum extension, where velocity is zero but acceleration is at its peak. The confusion often arises from misunderstanding the relationship between velocity and acceleration, where acceleration represents the rate of change of velocity. Ultimately, it is possible to have instantaneous zero velocity alongside non-zero acceleration.