Voltmeter values drop w/ time when measuring elec chem cell?

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The discussion centers on the observation that the voltage reading from a zinc-copper electrochemical cell decreases over time when using lemon juice as the electrolyte. This phenomenon is attributed to electrochemical cell polarization, where the voltmeter draws current, impacting the cell's performance. Participants confirm that such voltage decline is typical for homemade cells. They suggest that using copper sulfate solution instead of lemon juice could enhance performance, though caution is advised due to toxicity. Overall, the voltage drop is a normal occurrence in these types of electrochemical cells.
mizzmarymary
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I set up a zinc-copper elctrochemical cell by placing both electrodes in lemon juice to test the ability of lemon juice to conduct a current. I used a voltmeter and attached each lead to one of the metal electrodes. What I observed was that the voltage over time given on the voltmeter began to decrease and continued to decrease. I would be grateful if someone could explain what is happening? Thanks so much!
Mary
 
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How long did the process take?
The voltmeter draws some current and the cell does not run forever.
 
See "electrochemical cell polarization".
What you see is normal for these home made cells.
 
nasu said:
See "electrochemical cell polarization".
What you see is normal for these home made cells.
These cells work better if you use copper sulfate solution instead of the lemon juice. Careful, it is toxic.
 

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