No.
If you simply equated eV = 1/2mv^2, you would end up getting a relativistic value for the speed which is ridiculous.
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Here is how to derive the momentum of an electron:
p = mv (1)
eV = 1/2mv^2 (2)
These are 2 separate expressions
What we can do to number (2) is rearrange it for v and substitute into equation number (1)#
So number (2) becomes:
sqrt(2eV/m) = v (where aqrt stands for square root). Substitute this into v for (1):
p = m sqrt(2eV/m)
Square both sides and get rid of one of the m's, and square root again. Final expression for momentum should be:
p = sqrt(2meV)
h (plancks constant) is 6.63E-34
You should end up getting a wavelength of 5.49E-12m, I'm sure you can imagine why this would give a better resolution (when veiwing a microscope) than an optical microscope with wavelengths of 500nm.
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HOWEVER
I'm unsure whether to bring relativity into this. Because I did use KE = eV straight off the bat and the electron was moving at an extremely relativistic velocity. I decided I would calculate it's momentum by using it's rest mass, kinetic energy and total energy, but I ended up with an unuseable value. If you were supposed to apply laws of relativity to this equation then ignore what I said.
Can a more experienced individual please advise, I don't want to give some wrong answers.