One way to think of the Laplace transform is to compare it to the Fourier transform.
The Fourier transform is sort of like Fourier series, except Fourier series can only represent a periodic function, or, alternatively, a function defined only on an interval. So, you let that interval go to infinity in length and you get the Fourier transform, rather than Fourier series. In the case of Fourier series, you only have a discrete set of frequencies, but in taking this limit, the frequency becomes a continuous variable.
The Fourier transform is a function that takes in a frequency and the function value on that frequency tells you how much of that frequency is present in the function. So, the Fourier transform is kind of like a prism that takes the white light (many different frequencies) and splits it into its components, (red, blue, green--single frequencies).
So, the Laplace transform just gives you an extra dial to turn. With the Fourier transform, you turn the dial to specify what frequency component you want. But with the Laplace transform, you have another dial that allows you to express things in terms of damped sine and cosine functions, rather than just sine and cosine. So, you put in a real part that gives you the damping, and then the imaginary part that tells you what frequency you want. So, when you put a complex number into the Laplace transform of a function, you are asking it how much of some frequency is there when you try to express the function in terms of damped sine and cosine functions. When I say damped, I meaned multiplied by e^(-a), where a is the real part of s. So, actually, it will not really be damped if a is non-positive.