What happens at energy-gaps, Kronig-Penney model

  • Thread starter iAlexN
  • Start date
  • Tags
    Model
In summary, the conversation discusses the behavior of wave-functions in periodic boundaries in 1D, specifically in regards to energy gaps as explained by the Kronig-Penney model. The question is whether the wave-function remains continuous or changes in these regions. It is noted that for free electrons, the wave-functions are continuous as a function of k and E, but the periodic potential lifts this degeneracy and introduces different energies for the functions cos kx and sin kx.
  • #1
iAlexN
16
0
I'm studying periodic boundaries in 1D for which energy gaps occur, i.e. values of the energy which are not allowed, according to the Kronig-Penney model. My question is when these band gaps occur what happens to the wave-function, because it still has to be continuous, so it can't just terminate, so does it stay the same? Or what happens to the wave-function at these regions?

Thanks!
 
  • #3
The wavefunctions don't have to be continuous as a function of E, the spectra of atoms or molecules serve as a counter example. For free electrons, the wavefunctions are somehow continuous as a function of k and E, but, there are always two degenerate solutions with the same value of E, namely those with k and -k. The periodic potential will lift this degeneracy, i.e. while for a free particle the functions exp ikx and exp -ikx, or equivalently, cos kx and sin kx are degenerate, with a weak potential, the functions cos kx and sin kx are eigenfunctions belonging to different energies.
 

1. What is the Kronig-Penney model?

The Kronig-Penney model is a mathematical model used in solid-state physics to describe the behavior of electrons in a periodic potential. It was developed by Ralph Kronig and Walter Penney in the 1930s.

2. What is an energy gap in the Kronig-Penney model?

An energy gap in the Kronig-Penney model refers to a range of energies in which electrons cannot exist within a crystal lattice. This is due to the periodic potential of the lattice, which creates forbidden energy states.

3. How are energy gaps formed in the Kronig-Penney model?

Energy gaps are formed in the Kronig-Penney model due to the periodic potential of the crystal lattice. This potential creates regions of high and low energy that electrons cannot occupy, resulting in energy gaps.

4. What happens to electrons at energy gaps in the Kronig-Penney model?

At energy gaps, electrons cannot exist within the crystal lattice. This means that they are either reflected back or transmitted through the lattice depending on the energy of the electron and the width of the energy gap.

5. How does the Kronig-Penney model explain the properties of materials?

The Kronig-Penney model is used to explain the electronic properties of materials, such as electrical conductivity and optical properties. By understanding how electrons behave in a periodic potential, scientists can better understand and predict the properties of different materials.

Similar threads

Replies
7
Views
874
Replies
2
Views
2K
  • Atomic and Condensed Matter
Replies
1
Views
2K
  • Quantum Physics
Replies
21
Views
404
Replies
75
Views
3K
Replies
5
Views
293
Replies
2
Views
1K
  • Quantum Physics
2
Replies
36
Views
1K
Replies
13
Views
1K
  • Quantum Physics
Replies
24
Views
1K
Back
Top