Pressure DIFFERENCE is not linear: 2 atm is twice 1 but 3 atm is only 1.5x 2. So the percentage change is indeed greater the closer you are to the surface.
So consider that when you swim from 66 to 33 feet the air in your lungs wants to occupy 33% more volume but when you go from 33 to 0 it wants to occupy twice the volume.
Russ has put his finger on the issue. Volume expansion increases geometrically with ascent.
But why did you state this and then introduce pressure difference, Russ?
Whatever units you measure in, pressure difference is is linear. There is exactly the same pressure difference between 1 atm and 2 atm and 1000 atm and 1001 atm.
For diving purposes we can treat water as an incompressible fluid so pressure
of water increases linearly with depth in accordance with the elementary equation
Edit add surface pressure to equation.
P=pgD + P
s
Where P
s is the pressure at the surface , ie atmospheric pressure.
Now we introduce air, which is compressible and dive.
There are
two different scenarios.
1) If we take a breath at the surface and dive, we breath air at surface pressure and rely on the structure of our bodies to resist the increased pressure at depth. The air in our lungs is not in pressure equilibrium with the water pressure, even at very shallow depths. this is why if we open our mouths water will enter. There may be some slight pressurisation of the lung air, but it never deviates far from the surface pressure and returns to surface on our return.
2) At some depth if we breath air pressurised to be in equilibrium with the water pressure and open our mouths under water at that depth, water will not enter. This is in fact a divers show off trick (not recommended).
As we ascend the air in our lungs will try to expand as it is now at higher pressure than the surrounding water. this is why divers are taught to breath out on ascent.
Given the above information I conclude there is more to Dave's story yet to be told.