What Materials Cannot Use the Electric Potential Energy Law?

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stefano colom
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my professor has explained Electric potential energy Law U=∫D*E above all the space. he said you can not use for some kind of materials. l can 't remember if they are Ferroelectricity or piezoelectric materials. then can you say to me the reason too? thank you
 
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but why couldn't l use for the ferroelectricity materials