The discussion explores how photons interact with different materials, specifically why they pass through transparent substances but reflect off polished surfaces. It highlights that photons are absorbed and re-emitted by electrons, with their re-emission angle determined by Maxwell's equations. Quantum mechanics is noted to align with classical theory when considering large numbers of photons, while Feynman's path-integral formulation suggests that photons take all possible paths and interfere with themselves. The conversation also touches on the limitations of popular explanations that do not allow for practical calculations. Overall, the interaction of photons with materials is complex and involves both classical and quantum principles.