Whenever a impurity is added to the semicondutor i.e. silicon or Ge

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Impurities added to semiconductors like silicon and germanium are typically chosen from groups 13 and 15 of the periodic table due to their favorable electrical properties. These elements, such as boron and phosphorus, effectively alter the semiconductor's conductivity without disrupting the crystal structure. In contrast, elements from group 17 may bond too readily, potentially leading to undesirable effects. Additionally, group 12 elements do not provide the necessary charge carriers to enhance semiconductor performance. Understanding the crystal structure and compatibility of dopants is crucial for optimizing semiconductor functionality.
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whenever a impurity is added to the semicondutor i.e. silicon or Ge ,why the impurity is chosen from group 13 and 15?why not from group 17 or 12 from periodic table?
 
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My guess is that it's more based on electrical properties of a particular substance rather than bonding properties or physical properties... and group 17 might bond too readily. But I'm certainly no expert
 


Look at the crystal structure of the host matrix and then look for atoms that will fit.
 


now that you say that I remember having read it somewhere
 
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