Which Pairing Is Not a Set of Conjugates?

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The discussion centers on identifying which pairing is not a set of conjugates among several chemical pairs. The consensus is that conjugates differ by exactly one proton, while the pair H2SO4 and SO42– does not meet this criterion due to the stepwise dissociation of sulfuric acid. Participants clarify that H2SO4 first becomes HSO4– before it can form SO42–, indicating that SO42– is not a direct conjugate of H2SO4. The confusion arises from misunderstanding the definition of conjugate pairs in acid-base chemistry. Ultimately, the correct answer is that E (H2SO4 and SO42–) is not a pair of conjugates.
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Homework Statement


Which pairing is not a set of conjugates?

A. OH1– and H2O
B. HC2H3O2 and C2H3O21–
C. HCl and Cl1–
D. NH3 and NH41+
E. H2SO4 and SO42–

Homework Equations


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The Attempt at a Solution


I couldn't choose because conjugates, from what I learnt, is basically an acid or a base and its equivalent with more or less protons. All of the pairs have protons as their only difference. The only special case is E with 2 proton difference, but I know H2SO4 is sulfuric acid and when it has donated its protons it will become SO42–. So it seems to me E would also be conjugate. However, the answer is E. Could someone explain to me why E is not a pair of conjugates?
 
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TT0 said:
conjugates, from what I learnt, is basically an acid or a base and its equivalent with more or less protons

That's imprecise. Acid and its conjugate base differ by exactly one proton.

Please remember, that sulfuric acid dissociates stepwise:

H2SO4 ↔ HSO4- + H+

and

HSO4- ↔ SO42- + H+

Can you show now conjugate pairs in this process?
 
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