The main problem with what you want to do is you don't see super capacitors much over 2.7V tolerance and if you can find them higher they get crazy expensive. As mentioned you have to string a bunch in series to get to a 48V tolerance, like 20 of them. The problem with putting them in series is capacitance reduces similar to resistors in parallel. So after you put 20 of them in series to get that 48V tolerance you end up with a 20th the capacitance which will be a problem driving a motor any length of time.
The reason super capacitors can be dangerous is they have very low internal impedance so very large instantaneous currents can occur if terminals are shorted. It can be a rather explosive event. You do have to be careful with them when charged. Also you have to be careful about over-charging them or they can break down internally resulting in the same event. So yeah the PF moderators may shut down the thread if they feel it's an overly hazardous topic.
Curious why a Li-Ion battery can not do the job for you. They have their hazards as well, but still a lot safer. A 12S Li-Ion battery could do the job with a nominal 44.4V. You can get a couple small 6S hobby style LiPo batteries off the shelf fairly cheap and run them in series.