sheaf said:
... Is there any agreed way that people heuristically think about the measurement process ?
The spin networks are the eigenvectors of area and volume operators. The labels on the network determine a certain amount of volume for each node and a certain amount of area assigned to each link.
In order to have a meaningful measurement of volume there must be some physically defined region. Heuristically, think of a region defined in some covariant way, by a physical object or some definite events. Then there is an associated volume observable.
In the state specified by a particular spin network, the volume is just the sum of all the volumes belonging to the nodes of the network which are inside the volume. (I duck the question of borderline cases.)
Or there is some physically defined surface---a desktop?!, an horizon of some type?---and you look at the set of all the links in the network which are CUT by this surface, and add up all the area numbers which are associated with those cut links.
John Baez might have a "This Week's Finds" about this from some years back. He's good with heuristics. Or Rovelli if you find something of his written for beginners, where he wants to make it intuitive.
The nodes of the network can symbolize chunks of volume (that could be revealed by measurement) and the links can stand for flakes of area bounding the chunks. Intuitively if you specify all the possible areas and volumes that you could measure, then you have somehow determined the geometry of the universe. The state of geometry of the universe is somehow revealable by taking all possible area and volume measurements.
I guess there could be other combinations of different sorts of geometric measurements that would also determine a geometric state. There could be some other basis for the kinematic Hilbertspace. Eigenvectors of some other types of geometric measurement.
I'm not a loop gravity expert, but you asked for some heuristic and I can offer a bit of personal intuition. Have you tried Rovelli's book, an online draft is available free for download, or any of the various introductory articles. What level are you trying to go in at?