When two objects are rubbed together, one gains a negative charge while the other gains a positive charge, as charge is conserved. Electrons, which are loosely bound in the outer shells of atoms, can move easily between objects, while protons remain fixed in the nucleus. The specific outcome of which object gains or loses electrons depends on the materials involved, as indicated by their electron affinity. The Triboelectric Series provides a reference for predicting the charge transfer between different materials. Understanding these principles clarifies why the charge transfer is not arbitrary and depends on the properties of the objects being rubbed together.