Why do some Lewis structures have exceptions?

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Lewis structures can have exceptions due to the limitations of the octet rule, particularly in molecules like ICl4^-, where iodine can expand its valence shell beyond eight electrons. In this case, iodine has 12 electrons after forming single bonds with four chlorine atoms, which is possible because it is a third-period element. The discussion raises concerns about handling odd electron counts in Lewis structures and the confusion surrounding determining central atoms and bond angles. A reliable guide for these concepts is sought, as existing resources are deemed inadequate. Understanding these exceptions is crucial for accurately representing molecular structures.
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Homework Statement



ICl_4^-

Homework Equations


n/a


The Attempt at a Solution



I has 7 valence, Cl has 7*4. Ideally, they would be 8 and 8*4, and so.
(40-35+1)/2 = 2 bonds. //the +1 is from the negative charge of the ion

There are simply not enough bonds to go around, so when I draw it out I just give a single bond to everything that needs it. Then I make sure that they all satisfy the octet rule and give the leftover electrons to the central atom (I)? So I end up with 4 Cl's with 6 electron dots single bonded to the I, which has an additional 2 lone pair. So I has 12 electrons?

I can understand this one as an example, but what happens when I come up with an odd number of electrons? Is there a decent guide to this somewhere? The only ones that I found are horrible. Also, I am confused as to how exactly you know to make a molecule have more than one central angle?
 
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It seems to me like you're sort of working backwards, and it's confusing you. Here's a guide: http://http-server.carleton.ca/~rburk/chem1000/on_line_tuts/vsepr/ICl4_.htm
 
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