LostConjugate said:
That is fascinating. So the free electrons in motion within the material are deviated from their course perpendicular to the field. What causes them to start moving in the direction of the field? Or did I miss something?
The electrons are already in motion technically. There is the random thermal motion of electrons, since we are talking about a metal here, in the conduction band. But this isn't what what really contributes to the magnetic properties, the conduction electrons are responsible for conduction currents (which are in response to both magnetic and electric fields, like in a wave where the electric field gives the primary movement to the charges and then the magnetic field gives a force on the moving charges). The actual physics get a bit muddy here because this is still a classical description. Classically, we view a material as being filled with microscopic loop currents. What these loop currents are do not have a true physical representation. A naive way to think of them would be that they are the electrons orbiting an atom, but this of course falls apart when we think about the true nature of the atom in terms of quantum mechanics. However, in quantum mechanics, the electrons do retain a magnetic moment so it is not that bad of an assumption. Modeling it as a loop current is not correct but the fact that they can have a magnetic moment is.
So the point is that these loop current have magnetic moments. Normally the moments are randomly oriented and thus cancel each other out. The permeability of a material is a measure of how much these moments will align in response to an applied magnetic field. That is, if we place a magnetic field throughout the material, the microscopic moments will find it energetically advantageous to align with the field, thus they experience a torque. Upon aligning, all these microscopic moments will be in the same direction and thus generate a macroscopically significant magnetic field. This is the magnetization field and is included in the B field of a problem. A ferrous material is special because it has large regions of the material where the moments are already commonly aligned. However, there are many many regions in the material and they too are randomly aligned. So these small regions again do not contribute to a net magnetic field. However, the application of an external magnetic field will align these regions and you get a strong magnetization. In addition, when we turn off the applied field, these domains will remain aligned, giving the ferrite a permanent (or lasting) magnetization. Thus, we now have a magnet.
Simply put then, the magnets are operating on the magnetic moments of the individual atoms which are created by the orbiting electrons. Part of this is by the electron spin in what is known as paramagnetism. Another magnetic moment is produced by the actual movement of the electrons around the atom, this is diamagnetism I believe. Ferromagnetism is like paramagnetism, but as I mentioned above, the moments do not need an applied field to line up, they will do so naturally.