Why do we need to supply air to the cathode of a hydrogen fuel cell

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Discussion Overview

The discussion focuses on the operation of hydrogen fuel cells, specifically the necessity of supplying air to the cathode. Participants explore the roles of various components in the fuel cell, including the anode, cathode, catalyst, and electrolyte, while questioning the implications of operating without air.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant seeks to understand the function of air at the cathode, questioning whether the fuel cell can operate without it.
  • Another participant prompts for clarification on what is produced when positive ions travel through the electrolyte without air.
  • A suggestion is made to start with the reaction equation to clarify the process involved.
  • It is noted that there is a limit to the accumulation of positive ions, implying that electrons are needed to neutralize these ions, which oxygen can provide, resulting in water formation.
  • A later contribution emphasizes that the equations must balance, indicating that electrons must return to the cell, with hydrogen giving up electrons and oxygen taking them to form water.

Areas of Agreement / Disagreement

Participants express varying levels of understanding regarding the necessity of air at the cathode, with some agreeing on the need for oxygen to balance the reaction while others question the implications of operating without it. The discussion remains unresolved regarding the complete understanding of the role of air in the fuel cell operation.

Contextual Notes

There are limitations in the discussion regarding the assumptions about the reactions occurring within the fuel cell and the specific conditions under which they operate. The exact mechanisms and dependencies on definitions of terms like "neutralize" and "balance" are not fully explored.

Who May Find This Useful

This discussion may be useful for individuals interested in the technical workings of hydrogen fuel cells, including students and professionals in the fields of chemistry, engineering, and renewable energy technologies.

srinaath
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I am trying to understand the working of simple hydrogen fuel cell.
We have anode (negative terminal), cathode (positive terminal), catalyst at anode to separate negative and positive ions of hydrogen atoms and electrolyte which allows only positive ions.

We will be sending hydrogen fuel at anode where both positive and negative ions separated. electrons goes through external wire providing electricity. Also i read that we will be sending air to cathode. Why is that required? I mean without air won't the system still work? positive ions will still travel though electrolyte

Kindly provide me some insight.
 
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srinaath said:
positive ions will still travel though electrolyte
Producing/yielding what?
 
Start with the reaction equation.
 
srinaath said:
positive ions will still travel though electrolyte
There is a limit to how many of those ions can accumulate in anyone place. You need to provide electrons to neutralise those positive ions. Oxygen will do that for you and hey Presto - you have neutral water.
 
At the end the equations must balance! --- Electrons that come out of the cell must return! H2 in one side and gives up an electron, and O2 in the other and takes an electron - when they meet in the middle - they get happy (lower energy state) and make water.

220px-Solid_oxide_fuel_cell_protonic.svg.png
 

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