Why does aluminum react exothermically with palladium?

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The reaction between aluminum and palladium is highly exothermic, particularly in the context of palladium-clad aluminum wires, known as Pyrofuze. This reaction initiates at 600 °C, the melting point of aluminum, and can reach temperatures between 2200-2800 °C. Notably, this reaction occurs without the need for oxygen, resulting in the complete consumption of the wire. Such characteristics make it a significant example of an exothermic alloying reaction.

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http://en.wikipedia.org/wiki/Pyrotechnic_initiator
Palladium-aluminium

Palladium-clad aluminium wires can be used as a fuse wire, known as Pyrofuze. The reaction is initiated by heat, typically supplied by electric current pulse. The reaction begins at 600 °C, the melting point of aluminium, and proceeds violently to temperature of 2200-2800 °C. The reaction does not need presence of oxygen, and the wire is consumed.

 
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Now THAT's an example of a very exothermic alloying reaction!
 

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